CQX  

Chemical formula:

Cu(C8H6N2)(Cl1-xBrx)2

Lattice type:


Monoclinic

How to grow:

Wet chemistry synthesis

Magnetic model:

S=1/2 spin ladder

Why is it cool:

A continuously tunable family of quantum spin ladders

CQC crystals

The family of copper quinoxaline halides is a rare example of the spin ladder materials in which the continuous chemical substituition of chloride with bromide can be carries out without any structural transitions. The exchange constants are clearly changing as the result of it, but not dramatically. Basically, CQX ladders always stay close to the "isotropic" limit with nearly equal leg and rung exchanges. The smallness of crystals and somewhat large energy scale make CQX a difficult target for most experimental techniques, but that is just ideal for Raman scattering. A two-magnon continuum in a ladder can be observed with ease by light scattering, and tracing this continuum as function of composition confirms the continuous nature of exchange constants tuning.   


CQX Raman
Spectrum of Raman scattering in Cu(Qnx)Cl2 and Cu(Qnx)Br2, with clearly visible broad continua of magnetic excitations.

G. Simutis, S. Gvasaliya, F. Xiao, C. P. Landee and A. Zheludev, Optical spin excitations in the tunable quantum spin ladder Cu(Qnx)(Cl1-xBrx)2;external page Phys. Rev. B 93, 094412 (2016); external page arXiv:1510.06360

K. Yu. Povarov, W. E. A. Lorenz, F. Xiao, C. P. Landee, Y. Krasnikova, A. Zheludev, The tunable quantum spin ladder Cu(Qnx)(Cl1-xBrx)2, external page JMMM 370, 62 (2014),  external page arXiv:1402.2532

B. C. Keith, F. Xiao, Ch. P. Landee, M. M. Turnbull, A. Zheludev, Random exchange in the spin ladder Cu(quinoxaline)X2 (X = Cl, Br), external page Polyhedron 30, 3006 (2011)

JavaScript has been disabled in your browser