BPCB

Chemical formula:

(C5H12N)2CuBr4

Lattice type:


Monoclinic

How to grow:

Wet chemistry synthesis

Magnetic model:

S=1/2 quantum spin ladder

Why is it cool:

An ideal strong-rung Heisenberg S=1/2 spin ladder with experimentally convenient energy scales.

BPCB crystal

BPCB was recognized as an outstanding spin ladder model material already back in the 90's. Spin 1/2 antiferromagnetic dimers are weakly coupled in a ladder-like structures, which are in turn well separated from each other. This particular pattern of interactions (strong rung ladder) allows to use a multitude of analytical approximations for both zero field gapped and field-induced gapless phases and the respective dynamic properties. Thanks to the overall low energy scale, the full phase diagram can be accessed and the measured properties can be compared with the theoretical predictions. BPCB has withstood a vast number of tests in this regard.

Some fundamental insights have been achieved in our group by using BPCB as a model material too. In particular, the long-standing predictions of zero-scale universality at z=2 d=1 critical point (or simply at the field that closes the gap) were verified. Also BPCB has turned out to be a good case to study the effect of weak anisotropic interactions in the gapped phase, where they split the spectrum, near the critical points where they create magnonic bound states, and deep in the Luttinger liquid state where they lead to formation of solitonic excitations.


Scaling in BPCB
Magnetic spectra of BPCB near quantum criticality, measured on a time-of-flight neutron spectrometer LET

Yu. V. Krasnikova, S. C. Furuya, V. N. Glazkov, K. Yu. Povarov, D. Blosser, A. Zheludev, Anisotropy-induced soliton excitation in magnetized strong-rung spin ladders, external page Phys. Rev. Lett. 125, 027204 (2020); external page arXiv:2006.14899

M. Nayak, D. Blosser, A. Zheludev and F. Mila, Magnetic field induced bound states in spin-​1/2 ladders, external page Phys. Rev. Lett. 124, 087203 (2020); external page arXiv:1912.01576

D. Blosser, V. K. Bhartiya, D. J. Voneshen, A. Zheludev, Origin of magnetic anisotropy in the spin ladder compound (C5H12N)2CuBr4, external page Phys. Rev. B 100, 144406 (2019); external page arXiv:1908.00724

D. Blosser, V. K. Bhartiya, D. J. Voneshen, A. Zheludev, z=2 quantum critical dynamics in a spin ladder, external page Phys. Rev. Lett. 121, 247201 (2018); external page arXiv:1806.10392

JavaScript has been disabled in your browser